Sperm can survive in fertile cervical mucus for up to five days; the egg is viable for roughly 12–24 hours. That asymmetry is why the days before ovulation matter more than the day after.
Studies consistently show the highest conception rates in the two days before ovulation and on the day itself. Having sex every one to two days across the fertile window performs about as well as trying to hit an exact hour, and is far less stressful.
Daily ejaculation does not meaningfully deplete sperm counts in most men, and long abstinence does not improve outcomes — sperm quality tends to decline after several days of abstinence.